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KMID : 1134820090380121779
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Journal of the Korean Society of Food Science and Nutrition
2009 Volume.38 No. 12 p.1779 ~ p.1784
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Monitoring of Ergosterol Biosynthesis Inhibitor (EBI) Pesticide Residuesin Commercial Agricultural Products and Risk Assessment
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Lee Hee-Jung
Choe Won-Jo
Lee Ju-Young
Kang Chan-Soon
Kim Woo-Seong
Cho Dae-Hyun
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Abstract
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Establishment of simultaneous analysis method and monitoring for individually analyzing residual eight ergosterol biosynthesis inhibitors, EBI (difenoconazole, diniconazole, fenarimol, fenbuconazole, hexaconazole, myclobutanil, nuarimol and paclobutrazol) pesticides in commercial agricultural products, were conducted. The simultaneous analysis method for the pesticides was established using a GC/MS/MS for EBI pesticides. Residual amount of those pesticides were investigated in 989 commercial agricultural products (fifteen kinds of cereal grains, vegetables, beans, nuts, fruits and mushrooms) from seven metropolitan cities and eight provinces. In EBI pesticides analysis, linearity of GC/MS/MS analysis was 0.9974~0.9992, and that of recoveries were 86~135% with relative standard deviations (RSD) ＜20%. The limit of quantification (LOQ) of the method ranged from 0.5 to 5.0 ㎎/㎏ for eight EBI pesticides. According to the monitoring of the EBI pesticides in commercial agricultural products, difenoconazole, fenarimol, hexaconazole showed various residual levels (total frequency of 8/989 detection, 0.8%). Paclobutrazole showed in excess levels of the MRLs (maximum residue limits) for pesticides in one chard sample by the Korea Food Code. As a result of exposure assessment on the detected 8 individual pesticides, all pesticides (difenoconazole, fenarimol, hexaconazole, paclobutrazole) were evaluated as safe level in comparison to toxicologically acceptable daily intake.
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KEYWORD
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EBI (ergosterol biosynthesis inhibitor) pesticides, pesticide residue, exposure assessment
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